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Organic Chemistry. My earliest activities in this field include a modest and first-ever review article in cooperation with Dr.

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Hartog who at that time did his doctoral research on the Barbier reaction. References to this review article, as mentioned in the Science Citation Index till recently are a good indication for a continued interest in this simple synthetic procedure. The subtitle of this monograph, Related One-Step Processes, may require the following clarification.

A synthesis with the aid of an organometallic compound is usually carried out in two steps: 1 the organometallic reagent is prepared from an organo halide and a metal in a solvent, 2 a chosen substrate is added to this reagent. In a Barbier reaction these two steps are combined: a mixture of the organo halide and the substrate is added to a suspension of the metal-in an appropriate solvent.

Blomberg, Cornelis.

Grignard Reagent Reaction Mechanism

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The Barbier Reaction and Related One-Step Processes

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